YSZ

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YSZ

材料名称

牌号	材料名称	化学式	信息来源
brand	Name	Chemical Formula	Information Source
3	CaSZ	Zr0.85Ca0.15O1.85	LV Z G, YAO P, GUO R S, et al. Study on zirconia solid electrolytes doped by complex additives [J]. Mater Sci Eng: A, 2007, 458(1?2): 355?360.
4	NdSZ	(ZrO2)0.85(Nd2O3)0.15	FERGUS J W. Electrolytes for solid oxide fuel cells [J]. J Power Sources, 2006, 162(1): 30?40.
2	SSZ	(ZrO2)1-x(Sc2O3)X(X=0.08)	"SINGH K A, PATHAK L C, ROY S K. Effect of citric acid on the synthesis of nano-crystalline yttria stabilized zirconia powders by ni-trate?citrate process [J]. Ceram Int, 2007, 33(8): 1 463?1 468. "
5	SmSZ	(ZrO2)0.9(Sm2O3)0.1
1	YSZ	(ZrO2)1-x(Y2O3)X(X=0.08-0.1)	"KUO C W, LEE Y H, HUNG I M, et al. Crystallization kinetics and growth mechanism of 8 mol% yttria-stabilized zirconia (8YSZ) nano- powders prepared by a sol?gel process [J]. J Alloys Compd, 2008, 453(1?2): 470?475. "
6	YbSZ	(ZrO2)0.9(Yb2O3)0.1	"H.Yahiro，K.Eguchi,H.Arai.Oxygen ion conductivity of the ceria-samarium oxide system with fluorite structure[J].Electrochem Soc.135(1988)2077."

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生产工艺

牌号	名称	生产工艺	信息来源
Brand	Name	Manufacturing Technique	Information Source
3	CaSZ	固相法液相法	LV Z G, YAO P, GUO R S, et al. Study on zirconia solid electrolytes doped by complex additives [J]. Mater Sci Eng: A, 2007, 458(1?2): 355?360.
4	NdSZ	固相法液相法	FERGUS J W. Electrolytes for solid oxide fuel cells [J]. J Power Sources, 2006, 162(1): 30?40.
2	SSZ	固相法液相法	"SINGH K A, PATHAK L C, ROY S K. Effect of citric acid on the synthesis of nano-crystalline yttria stabilized zirconia powders by ni-trate?citrate process [J]. Ceram Int, 2007, 33(8): 1 463?1 468. "
5	SmSZ	固相法液相法
1	YSZ	固相法液相法	"KUO C W, LEE Y H, HUNG I M, et al. Crystallization kinetics and growth mechanism of 8 mol% yttria-stabilized zirconia (8YSZ) nano- powders prepared by a sol?gel process [J]. J Alloys Compd, 2008, 453(1?2): 470?475. "
6	YbSZ	固相法液相法	"H.Yahiro，K.Eguchi,H.Arai.Oxygen ion conductivity of the ceria-samarium oxide system with fluorite structure[J].Electrochem Soc.135(1988)2077."

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性能

牌号	制备YSZ粉料的方法	煅烧温度℃	颗粒度（微米）	理论密度%	比表面积m2/g	电导率S·cm	弯曲强度Mpa	热膨胀系数	信息来源
Brand	Preparation method	Calcination temperature	Particle size	Theoretical density	Specific area	Conductivity	Bending strength	Thermal expansivity	Information Source
	丙酮甲苯法	650	≤100	32	16
	醇盐法	650		12	90
2	固相法、溶胶凝胶法				34	掺杂量10%mol1000℃ 0.25		11.2×10-6	Etsell T H. Electrical properties of solid oxide electrolytes.Chem Rew,1970(3):339-376
3	固相法、液相法					1000℃0.08			R.I. Merino.Journal of the European Ceramic Society 24 (2004) 1349?1353
	过氧化物法	600	≤50	38	82
	氯化物法	650		10	123
	柠檬酸法	650		5	58	YSZ（9%Y2O3）600℃0.006	YSZ（8%Y2O3）1000℃ 225
1	热煤油法	600	2--20	18	4	YSZ（9%Y2O3）1000℃0.12	YSZ（8%Y2O3）25℃ 300	10.8×10-6	Minh N Q, Takahashi T.Science and technology of ceramic fuel cells.Elsevier,1995
	溶胶凝胶法	650	1--20	26	32
									Haruo Kishimoto,Teruhisa Horita.Solid State Ionics 175 (2004) 107-111
4						掺杂量15%mol1000℃ 1.4			Etsell T H. Electrical properties of solid oxide electrolytes.Chem Rew,1970(3):339-376
5						掺杂量10%mol1000℃ 5.8			Etsell T H. Electrical properties of solid oxide electrolytes.Chem Rew,1970(3):339-376
6						掺杂量10%mol1000℃ 11			Etsell T H. Electrical properties of solid oxide electrolytes.Chem Rew,1970(3):339-376
									Ze Lei,Qingshan Zhu.Journal of the European Ceramic Society 26 (2006) 397?401

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化学成分

牌号	名称	化学成分	信息来源
Brand	Name	chemical composition	Information Source
3	CaSZ	Ca Zr	LV Z G, YAO P, GUO R S, et al. Study on zirconia solid electrolytes doped by complex additives [J]. Mater Sci Eng: A, 2007, 458(1?2): 355?360.
4	NdSZ	Nd Zr	FERGUS J W. Electrolytes for solid oxide fuel cells [J]. J Power Sources, 2006, 162(1): 30?40.
2	SSZ	Sc Zr	"SINGH K A, PATHAK L C, ROY S K. Effect of citric acid on the synthesis of nano-crystalline yttria stabilized zirconia powders by ni-trate?citrate process [J]. Ceram Int, 2007, 33(8): 1 463?1 468. "
5	SmSZ	Sm Zr
1	YSZ	Y Zr	"KUO C W, LEE Y H, HUNG I M, et al. Crystallization kinetics and growth mechanism of 8 mol% yttria-stabilized zirconia (8YSZ) nano- powders prepared by a sol?gel process [J]. J Alloys Compd, 2008, 453(1?2): 470?475. "
6	YbSZ	Yb Zr	"H.Yahiro，K.Eguchi,H.Arai.Oxygen ion conductivity of the ceria-samarium oxide system with fluorite structure[J].Electrochem Soc.135(1988)2077."

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